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Photo‐crosslinkable NIR‐absorbing window with environmental stability

Hyunmin Hwang (Department of Organic Materials and Fiber Engineering, Soongsil University, Seoul, Korea)
Moon Sung Kang (Department of Chemical Engineering, Soongsil University, Seoul, Korea)
Jong Hun Han (Green Energy Research Center, Korea Electronics Technology Institute, Seongnam‐si, Korea)
Kwonwoo Shin (Green Energy Research Center, Korea Electronics Technology Institute, Seongnam‐si, Korea)
Jeong Ho Cho (Department of Chemical Engineering, Sungkyunkwan University, Suwon, Korea)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 17 May 2013

195

Abstract

Purpose

The authors aimed to develop environmentally stable NIR‐absorbing windows by blending a near‐infrared (NIR)‐absorbing dye and a photo‐crosslinkable polymer.

Design/methodology/approach

To prepare an environmentally stable NIR‐absorbing window, a NIR‐absorbing dye was mixed with crosslinkable poly(vinyl cinnamate) (PVCn). The crosslinking of PVCn was carried out by photo‐dimerisation reaction of cinnamate with UV‐exposure at a wavelength of 254 nm for 4 min.

Findings

The resistance of the photo‐crosslinked hybrid films against humidity, heat, and ultraviolet radiation damage was improved dramatically relative to the pristine NIR‐absorbing dye. These improvements result from the protection of NIR‐absorbing dye to moisture exposure in the presence of the polymer network.

Originality/value

The simple and practical method resulted in a dramatic improvement in the environmental stability of NIR‐absorbing window.

Keywords

Citation

Hwang, H., Sung Kang, M., Hun Han, J., Shin, K. and Ho Cho, J. (2013), "Photo‐crosslinkable NIR‐absorbing window with environmental stability", Pigment & Resin Technology, Vol. 42 No. 3, pp. 170-174. https://doi.org/10.1108/03699421311317334

Publisher

:

Emerald Group Publishing Limited

Copyright © 2013, Emerald Group Publishing Limited

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