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Pitting behavior and mechanism caused by Ca-Al-O-S composite inclusions in low-alloy steels

Fan Yi (Material Science and Engineering School, Yanshan University, Qinhuangdao, China and Nanjing Iron and Steel Group Coro, Nanjing, China)
Wang Qingfeng (Material Science and Engineering School, Yanshan University, Qinhuangdao, China)
Yang Wenxiu (Nanjing Iron and Steel Group Coro, Nanjing, China)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 6 March 2017

125

Abstract

Purpose

The purpose of this study is to study the pitting caused by Ca-Al-O-S composite inclusions of low-alloy steel in 3 Wt.% NaCl solution and 0.01M NaHSO3 solution.

Design/methodology/approach

The corrosion in 0.01M NaHSO3 was much weaker than in 3 Wt.% NaCl 3D display of the pitting formation and development process that has been calculated using scanning electron microscope (SEM) and laser scanning confocal microscopy (LSCM). In addition, a corrosion mechanism of pitting formation by galvanic interaction of composite inclusion and base metal has been proposed.

Findings

Results show that in immersion test, metal base around inclusions was dissolved due to corrosion. Corrosion on the metal base closer to inclusions was more severe.

Originality/value

A corrosion mechanism of pitting formation by galvanic interaction of composite inclusion and base metal has been proposed.

Keywords

Citation

Yi, F., Qingfeng, W. and Wenxiu, Y. (2017), "Pitting behavior and mechanism caused by Ca-Al-O-S composite inclusions in low-alloy steels", Anti-Corrosion Methods and Materials, Vol. 64 No. 2, pp. 218-224. https://doi.org/10.1108/ACMM-05-2016-1675

Publisher

:

Emerald Publishing Limited

Copyright © 2017, Emerald Publishing Limited

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