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Dyes from benzamide

Susai Rajendran (Department of Chemistry, GTN Arts College, Dindigul, India)
A. Peter Pascal Regis (Department of Chemistry, St Joseph’s College, Trichy, India)
D.C. Trivedi (Central Electrochemical Research Institute, Karaikudi, India)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 1 August 1999

379

Abstract

Aqueous sodium chloride solution, containing benzamide was electrolysed (pH = 2), using platinised titanium anode and graphite cathode. The filtrate of the reaction mixture (pH = 4.5) was diazotised and coupled with α‐naphthol in NaOH and also with β‐naphthol in NaOH. Dyes were produced. These dyes were matched with the standard dyes prepared from aniline. Uv‐visible absorption spectral study reveals that the dyes produced are slightly different from the standard dyes. During the course of the reaction benzamide is converted into aniline with a long chain polymeric unit having a free amino end; and/or a polymeric unit which generates a free amino end during the process of diazotisation.

Keywords

Citation

Rajendran, S., Pascal Regis, A.P. and Trivedi, D.C. (1999), "Dyes from benzamide", Pigment & Resin Technology, Vol. 28 No. 4, pp. 230-232. https://doi.org/10.1108/03699429910280747

Publisher

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MCB UP Ltd

Copyright © 1999, MCB UP Limited

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