The effects of Cl⁻ and direct stray current on soil corrosion of three grounding grid materials

Abstract

Purpose

The purpose of this paper is to study the effects of Cl⁻ and direct stray current on the soil corrosion of three grounding grid materials.

Design/methodology/approach

The electrochemical corrosion properties of three grounding grid materials, which include the Q235 steel, Q235 galvanized flat steel and copper, were measured by means of the weak polarization curve method and electrochemical impedance spectroscopy; the corrosion rate of specimens was calculated using the weight loss method; and the specimen surfaces were characterized using the scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction analysis.

Findings

Results showed that both factors, Cl⁻ and direct stray current, can accelerate the corrosion rate of grounding grid materials. The magnitude of DC stray current density affected the mass transfer type and response frequency of the anode and cathode reaction of grounding materials, while the Cl⁻ contents of the soil only affect the mass transfer rate of the electrode material from the electrochemical impedance spectroscopy diagrams. The electric field generated by the DC stray current caused Cl⁻ directed migration. The larger the DC stray current density, the greater the diffusion process and the greater the weight loss rate of the grounding grid materials that would have a logarithmic relationship with the Cl⁻ content at the same DC stray current density. The corrosion resistance of the three materials is copper > Q235 galvanized flat steel > Q235 flat steel.

Originality/value

The paper provides information regarding the relationship among Cl⁻, direct stray current and corrosion of three grounding grid materials by means of electrochemical impedance spectroscopy. Meanwhile the weight loss rate is the logarithmic relationship with the Cl⁻ content, which is useful for understanding the corrosion mechanism of Q235 steel, Q235 galvanized flat steel and copper under the condition of Cl⁻ and direct stray current in soil.

Citation

Zhu, Z., Shi, C., Zhang, Y. and Liu, Z. (2020), "The effects of Cl⁻ and direct stray current on soil corrosion of three grounding grid materials", Anti-Corrosion Methods and Materials, Vol. 67 No. 1, pp. 73-82. https://doi.org/10.1108/ACMM-06-2019-2136