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The brazing effect on the corrosion mechanism of a multilayer material with Cu

Ting Yuan (Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, China and Jiangsu Laboratory of Recycling and Reuse Technology for Mechanical and Electronic Products, Changshu, China)
Min-da Zhang (Jiangsu Alcha Aluminum Co Ltd, Changshu, China)
Jia-hui Ni (Jiangsu Changshu Advanced Materials Industrial Park, Changshu, China)
Ya-xuan Chen (Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, China)
Fei Geng (Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, China and Jiangsu Laboratory of Recycling and Reuse Technology for Mechanical and Electronic Products, Changshu, China)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 6 November 2017

614

Abstract

Purpose

The purpose of this paper is to compare corrosion behavior of a modified multilayer material with Cu before and after brazing process.

Design/methodology/approach

Sea water acidified accelerated tests (SWAATs), potentiodynamic polarization tests and scanning electron microscopy were used to study the corrosion behavior and macro/micro structures. Results indicate that the corrosion mechanisms of the sheets before and after brazing process are completely different.

Findings

The un-brazed material is uniform corrosion, while the brazed material has a high sensitivity to localized corrosion and loses cathodic protection to the core. It is found that brazing process causes copper transition from the core alloy into eutectic phases in the cladding, leading to higher Ecorr and different potential distribution compared with those of un-brazed materials.

Originality/value

For the modified multilayer material after brazing, there are two stages of corrosion. First, corrosion attack takes place along eutectic phases in the cladding material, and then core alloy dissolves by forming a galvanic couple with the nobler residual cladding.

Keywords

Acknowledgements

Open Research Fund (RRME-KF1608) by Jiangsu Key Laboratory of Recycling and Reuse Technology for Mechanical and Electronic Products of China; Project (Grant Nos. 11405014) supported by National Natural Science Foundation of China; Project (BY2015043-02) supported by Jiangsu Science and Technology Department of China.

Citation

Yuan, T., Zhang, M.-d., Ni, J.-h., Chen, Y.-x. and Geng, F. (2017), "The brazing effect on the corrosion mechanism of a multilayer material with Cu", Anti-Corrosion Methods and Materials, Vol. 64 No. 6, pp. 664-671. https://doi.org/10.1108/ACMM-07-2016-1688

Publisher

:

Emerald Publishing Limited

Copyright © 2017, Emerald Publishing Limited

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