TiO₂ and CeO₂ nanoparticles as lithium complex grease additives for enhanced lubricity

Abstract

Purpose

This paper aims to improve the tribological properties of lithium complex greases using nanoparticles to investigate the tribological behavior of single additives (nano-TiO₂ or nano-CeO₂) and composite additives (nano-TiO₂–CeO₂) in lithium complex greases and to analyze the mechanism of their influence using a variety of characterization tools.

Design/methodology/approach

The morphology and microstructure of the nanoparticles were characterized by scanning electron microscopy and an X-ray diffractometer. The tribological properties of different nanoparticles, as well as compounded nanoparticles as greases, were evaluated. Average friction coefficients and wear diameters were analyzed. Scanning electron microscopy and three-dimensional topography were used to analyze the surface topography of worn steel balls. The elements present on the worn steel balls’ surface were analyzed using energy-dispersive spectroscopy and X-ray photoelectron spectroscopy.

Findings

The results showed that the coefficient of friction (COF) of grease with all three nanoparticles added was low. The grease-containing composite nanoparticles exhibited a lower COF and superior anti-wear properties. The sample displayed its optimal tribological performance when the ratio of TiO₂ to CeO₂ was 6:4, resulting in a 30.5% reduction in the COF and a 29.2% decrease in wear spot diameter compared to the original grease. Additionally, the roughness of the worn spot surface and the maximum depth of the wear mark were significantly reduced.

Originality/value

The main innovation of this study is the first mixing of nano-TiO₂ and nano-CeO₂ with different sizes and properties as compound lithium grease additives to significantly enhance the anti-wear and friction reduction properties of this grease. The results of friction experiments with a single additive are used as a basis to explore the synergistic lubrication mechanism of the compounded nanoparticles. This innovative approach provides a new reference and direction for future research and development of grease additives.

Peer review

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-09-2023-0291/

Citation

Du, Z., He, Q., Wan, H., Zhang, L., Xu, Z., Xu, Y. and Li, G. (2024), "TiO₂ and CeO₂ nanoparticles as lithium complex grease additives for enhanced lubricity", Industrial Lubrication and Tribology, Vol. 76 No. 1, pp. 70-80. https://doi.org/10.1108/ILT-09-2023-0291