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Synthesis of modified poly(ester-amide) and alkyd resins based on phenolic and Schiff base compounds to study their biological and insecticide activity for surface coating applications

Roma G. Elfadel (Department of Chemistry, Faculty of Science, Arish University, Arish, Egypt)
Hala M. Refat (Department of Chemistry, Faculty of Science, Arish University, Arish, Egypt)
H. Abdelwahab (Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt)
Salem S. Salem (Botany and Microbiology Department, Faculty of Science (Boys), Al-Azhar University, Cairo, Egypt)
Mohamed A. Awad (Department of Zoology and Entomology, Faculty of Science (Boys), Al-Azhar University, Cairo, Egypt)
M.A.M. Abdel Reheim (Department of Chemistry, Faculty of Science, Arish University, Arish, Egypt)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 13 June 2023

57

Abstract

Purpose

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

Design/methodology/approach

Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.

Findings

The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.

Research limitations/implications

The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.

Originality/value

Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.

Keywords

Acknowledgements

The authors express their sincere thanks to Faculty of science (Boyes), Al-Azhar University, Cairo, Egypt for providing the necessary research facilities. The authors would like to acknowledge the facilities available at Faculty of Science, Arish University, Arish, Egypt.

Citation

G. Elfadel, R., M. Refat, H., Abdelwahab, H., S. Salem, S., Awad, M.A. and Abdel Reheim, M.A.M. (2023), "Synthesis of modified poly(ester-amide) and alkyd resins based on phenolic and Schiff base compounds to study their biological and insecticide activity for surface coating applications", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-03-2023-0031

Publisher

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Emerald Publishing Limited

Copyright © 2023, Emerald Publishing Limited

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