To read this content please select one of the options below:

Inhibition of mild steel corrosion in sodium chloride solution by apricot waste extract obtained from different solvent systems

Viktoria Vorobyova (Department of Physical Chemistry, National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», Kyiv, Ukraine)
Margarita Skiba (Department of Inorganic Substances and Ecology, Ukrainian State Chemical-Engineering University, Dnipro, Ukraine)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 28 June 2021

Issue publication date: 7 February 2022

93

Abstract

Purpose

This paper aims to investigate influence of extraction solvent on the efficacy of apricot pomace extract (APE) as a sustainable corrosion inhibitor for mild steel in sodium chloride solution.

Design/methodology/approach

The chemical profiles of the extracts were analyzed using gas chromatography–mass spectrometry. Total phenolic, total flavonoid content and antioxidant properties of the extracts were determined. Besides, gravimetric, potentiodynamic polarization and atomic force microscopy were used to study the corrosion inhibition. The effect of immersion period on inhibition efficiency was evaluated. The reaction mechanism of the inhibitor was also discussed.

Findings

Corrosion inhibition decreasing is in the following order: solution of 2-propanol/ethanol apricot pomace (E/PAPE) extract > ethanol (EAPE) > 2-propanol (PAPE). The gravimetric, polarization measurements and surface analysis revealed that the growth of inhibitory properties is prolonged, and corrosion rate reduction after 40–48 h of exposure was studied.

Practical implications

APEs play an important role in the corrosion inhibition of mild steel in sodium chloride solution. Moreover, its application is potentially possible in industries.

Social implications

The results contribute to the integrated valorization of food waste.

Originality/value

The different compositions of the conversion/oxidation products of organic substances in solution were studied. The formation of polymerized flavanol-aldehyde adducts and oxidized quinone compounds or tautomers structures because of extract transformation in water causes main corrosion reduction in 40–48 h.

Keywords

Acknowledgements

This work was supported by the Ministry of Education and Science of Ukraine [grant no. 2403, 2021].

Citation

Vorobyova, V. and Skiba, M. (2022), "Inhibition of mild steel corrosion in sodium chloride solution by apricot waste extract obtained from different solvent systems", Pigment & Resin Technology, Vol. 51 No. 2, pp. 178-185. https://doi.org/10.1108/PRT-04-2020-0040

Publisher

:

Emerald Publishing Limited

Copyright © 2021, Emerald Publishing Limited

Related articles