Applications of gas chromatography in the paint & allied industries. Raw materials: Part 2

Abstract

The liquid extract obtained from the natural cashew nutshell is rich in phenolic substances which are derived from anacardic acid C6H3(OH) (CO2H) (C15H31‐n), where n may have values of 0, 2, 4 or 6 and represents various degrees of unsaturation in the aliphatic C15 side‐chain. Industrial decarboxylation of this material affords cardanol C6H4(OH) (C15H31‐n) plus other substituted phenols and polymeric residues. Tyman et al. (197, 198) have studied the analysis of all these products using GC, molecular distillation, TLC and mass spectrometry. After hydrogenation and the formation of the corresponding methyl esters, the products were analysed by GC using glass columns (5ft × 3/16in) packed with acid washed and silanized Diatomite as support material and which was coated with non‐polar stationary phases such as SE30, SE25 or APL, or semi‐polar phases such as 0V17, Dexil 300 or PEGA. Alternatively, the samples were subjected to an acetylation procedure prior to GC examination on columns containing Dexil 300, SE30 or SE52. The GC equipment consisted of a Pye‐Unicam model 104 instrument operated with nitrogen carrier gas (flow rate 45cm3 min−1) and equipped with FID.

Citation

Walton, A.J. (1981), "Applications of gas chromatography in the paint & allied industries. Raw materials: Part 2", Pigment & Resin Technology, Vol. 10 No. 1, pp. 4-10. https://doi.org/10.1108/eb041656