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Surface characterization of mild steel exposed to atmosphere after being treated by sodium benzoate and dicyclohexylamine nitrite

Ramazan Kahraman (Department of Chemical Engineering, Qatar University, Doha, Qatar)
Huseyin Saricimen (Research Institute (Center of Engineering Research), King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia and Department of Industrial Engineering, Yalova University, Yalova, Turkey)
Zuhair Omar Malaibari (Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia)
Md Abdur Rauf (Department of Chemical and Petroleum Engineering, United Arab Emirates University, Al Ain, United Arab Emirates)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 1 January 2016

124

Abstract

Purpose

The purpose of this study was to investigate the performances of two inhibitors in controlling corrosion of steel products in industrial and marine atmosphere.

Design/methodology/approach

Corrosion rates were determined by weight loss measurements. At certain periods of atmospheric exposure, the (disc shape) specimens were retrieved and studied by scanning electron microscopy and energy-dispersive spectrometry surface analysis techniques.

Findings

Both inhibitors were effective against corrosion of steel in the early stages of the atmospheric exposure (for about two months). With further exposure to the atmosphere, their inhibition effectiveness deteriorated and was totally lost within four months. Analysis of the specimens before exposure showed that the inhibitor film was thin for both treatments, and the unexposed treated surface for both inhibitors appeared similar to the untreated unexposed specimen surface. Characterization of the specimens at different exposure periods showed fewer corrosion blisters on dicyclohexylamine nitrite- and sodium benzoate-treated surfaces than on untreated specimens.

Originality/value

The objective of this study was to characterize the surfaces of the steel products produced locally during their exposure to the industrial and marine atmosphere of the Arabian Gulf region after being treated by sodium benzoate and dicyclohexylamine nitrite in controlling the corrosion of local mild steel products. According to the literature review, this study is original and will add value to the studies of inhibition of steel corrosion under similar environments.

Keywords

Acknowledgements

This project has been funded by King Abdulaziz City for Science and Technology under Project # ARP 19-10. The authors also acknowledge the support provided by King Fahd University of Petroleum & Minerals and Qatar University for this work.

Citation

Kahraman, R., Saricimen, H., Malaibari, Z.O. and Abdur Rauf, M. (2016), "Surface characterization of mild steel exposed to atmosphere after being treated by sodium benzoate and dicyclohexylamine nitrite", Anti-Corrosion Methods and Materials, Vol. 63 No. 5, pp. 337-346. https://doi.org/10.1108/ACMM-09-2014-1427

Publisher

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Emerald Group Publishing Limited

Copyright © 2016, Emerald Group Publishing Limited

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