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The tribochemical study of novel phosphorous-nitrogen (P-N) type phosphoramidate additives in water

Jincan Yan (School of Chemistry and Chemical Engineering, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Shanghai Jiaotong University, Shanghai, PR China)
Xuefeng Bai (School of Chemistry and Chemical Engineering, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Shanghai Jiaotong University, Shanghai, PR China)
Jing Li (YaoPharma Co. Ltd., Chongqing, China)
Tianhui Ren (School of Chemistry and Chemical Engineering, Key Laboratory for Thin Film and Microfabrication of the Ministry of Education, Shanghai Jiaotong University, Shanghai, PR China, and)
Yidong Zhao (Institute of High Energy Physics, Chinese Academy of Sciences, Beijing Synchrotron Radiation Facility, Beijing, China)

Industrial Lubrication and Tribology

ISSN: 0036-8792

Article publication date: 8 April 2014

188

Abstract

Purpose

The purpose of this paper is to investigate the tribological properties of novel phosphorous-nitrogen (P-N) type additives in water.

Design/methodology/approach

The tribological properties of the novel P-N additives in water are compared with a commercial lubricant additive of the P-N type using a four-ball machine. The tribological mechanism was investigated by X-ray absorption near-edge structure (XANES) spectroscopy.

Findings

The experimental results indicate that the phosphoramidate derivatives possess good anti-wear and friction-reducing properties. The XANES analysis shows that the prepared compounds can form a protective film containing phosphate and/or polyphosphate that affects the tribological behavior.

Originality/value

The purpose of this paper is to investigate the tribological properties of the novel P-N type additives in water.

Keywords

Acknowledgements

The authors are grateful to the National Natural Science Foundation of China (Grant No. 20872092) and Beijing Synchrotron Radiation Facility (Grant No. SR06033) for the financial support to the work reported here. They also gratefully thank Beijing Synchrotron Radiation Facility for the XANES analysis.

Citation

Yan, J., Bai, X., Li, J., Ren, T. and Zhao, Y. (2014), "The tribochemical study of novel phosphorous-nitrogen (P-N) type phosphoramidate additives in water", Industrial Lubrication and Tribology, Vol. 66 No. 3, pp. 346-352. https://doi.org/10.1108/ilt-12-2011-0111

Publisher

:

Emerald Group Publishing Limited

Copyright © 2014, Emerald Group Publishing Limited

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